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Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chir...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017490/ https://www.ncbi.nlm.nih.gov/pubmed/29596367 http://dx.doi.org/10.3390/molecules23040792 |
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author | Simões, Mário M. Q. Gonzaga, Daniel T. G. Cardoso, Mariana F. C. Forezi, Luana da S. M. Gomes, Ana T. P. C. da Silva, Fernando de C. Ferreira, Vítor F. Neves, Maria G. P. M. S. Cavaleiro, José A. S. |
author_facet | Simões, Mário M. Q. Gonzaga, Daniel T. G. Cardoso, Mariana F. C. Forezi, Luana da S. M. Gomes, Ana T. P. C. da Silva, Fernando de C. Ferreira, Vítor F. Neves, Maria G. P. M. S. Cavaleiro, José A. S. |
author_sort | Simões, Mário M. Q. |
collection | PubMed |
description | Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial. |
format | Online Article Text |
id | pubmed-6017490 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-60174902018-11-13 Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group Simões, Mário M. Q. Gonzaga, Daniel T. G. Cardoso, Mariana F. C. Forezi, Luana da S. M. Gomes, Ana T. P. C. da Silva, Fernando de C. Ferreira, Vítor F. Neves, Maria G. P. M. S. Cavaleiro, José A. S. Molecules Review Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial. MDPI 2018-03-29 /pmc/articles/PMC6017490/ /pubmed/29596367 http://dx.doi.org/10.3390/molecules23040792 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Simões, Mário M. Q. Gonzaga, Daniel T. G. Cardoso, Mariana F. C. Forezi, Luana da S. M. Gomes, Ana T. P. C. da Silva, Fernando de C. Ferreira, Vítor F. Neves, Maria G. P. M. S. Cavaleiro, José A. S. Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title | Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title_full | Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title_fullStr | Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title_full_unstemmed | Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title_short | Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group |
title_sort | carbene transfer reactions catalysed by dyes of the metalloporphyrin group |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017490/ https://www.ncbi.nlm.nih.gov/pubmed/29596367 http://dx.doi.org/10.3390/molecules23040792 |
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