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Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group

Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chir...

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Detalles Bibliográficos
Autores principales: Simões, Mário M. Q., Gonzaga, Daniel T. G., Cardoso, Mariana F. C., Forezi, Luana da S. M., Gomes, Ana T. P. C., da Silva, Fernando de C., Ferreira, Vítor F., Neves, Maria G. P. M. S., Cavaleiro, José A. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017490/
https://www.ncbi.nlm.nih.gov/pubmed/29596367
http://dx.doi.org/10.3390/molecules23040792
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author Simões, Mário M. Q.
Gonzaga, Daniel T. G.
Cardoso, Mariana F. C.
Forezi, Luana da S. M.
Gomes, Ana T. P. C.
da Silva, Fernando de C.
Ferreira, Vítor F.
Neves, Maria G. P. M. S.
Cavaleiro, José A. S.
author_facet Simões, Mário M. Q.
Gonzaga, Daniel T. G.
Cardoso, Mariana F. C.
Forezi, Luana da S. M.
Gomes, Ana T. P. C.
da Silva, Fernando de C.
Ferreira, Vítor F.
Neves, Maria G. P. M. S.
Cavaleiro, José A. S.
author_sort Simões, Mário M. Q.
collection PubMed
description Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.
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spelling pubmed-60174902018-11-13 Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group Simões, Mário M. Q. Gonzaga, Daniel T. G. Cardoso, Mariana F. C. Forezi, Luana da S. M. Gomes, Ana T. P. C. da Silva, Fernando de C. Ferreira, Vítor F. Neves, Maria G. P. M. S. Cavaleiro, José A. S. Molecules Review Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial. MDPI 2018-03-29 /pmc/articles/PMC6017490/ /pubmed/29596367 http://dx.doi.org/10.3390/molecules23040792 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Simões, Mário M. Q.
Gonzaga, Daniel T. G.
Cardoso, Mariana F. C.
Forezi, Luana da S. M.
Gomes, Ana T. P. C.
da Silva, Fernando de C.
Ferreira, Vítor F.
Neves, Maria G. P. M. S.
Cavaleiro, José A. S.
Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title_full Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title_fullStr Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title_full_unstemmed Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title_short Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group
title_sort carbene transfer reactions catalysed by dyes of the metalloporphyrin group
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017490/
https://www.ncbi.nlm.nih.gov/pubmed/29596367
http://dx.doi.org/10.3390/molecules23040792
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