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Asymmetric Total Synthesis of Four Stereoisomers of the Sex Pheromone of the Western Corn Rootworm

A convergent synthesis of four stereoisomers of the sex pheromone of the western corn rootworm (8-methyldecan-2-yl propionate, 1) from commercially available chiral starting materials is reported. The key step was Julia–Kocienski olefination between chiral BT-sulfone and chiral aldehyde. This synthe...

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Detalles Bibliográficos
Autores principales:	Sun, Zhi-Feng, Zhang, Tao, Liu, Jinyang, Du, Zhen-Ting, Zheng, Huaiji
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2018
Materias:	Communication
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017750/ https://www.ncbi.nlm.nih.gov/pubmed/29543774 http://dx.doi.org/10.3390/molecules23030667

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