Catalytic Annulation of Epoxides with Heterocumulenes by the Indium-Tin System

In the synthesis of five-membered heterocycles by the annulation of epoxides with heterocumulenes such as carbon dioxide and isocyanates, we developed the indium-tin catalytic system and synthesized various cyclic adducts including novel types products under mild reaction conditions.

Detalles Bibliográficos
Autores principales: Suzuki, Itaru, Imakuni, Akira, Baba, Akio, Shibata, Ikuya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017780/
https://www.ncbi.nlm.nih.gov/pubmed/29597316
http://dx.doi.org/10.3390/molecules23040782
Descripción
Sumario:In the synthesis of five-membered heterocycles by the annulation of epoxides with heterocumulenes such as carbon dioxide and isocyanates, we developed the indium-tin catalytic system and synthesized various cyclic adducts including novel types products under mild reaction conditions.

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