Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)

Anionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physi...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, E, Jian, Fangfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017829/
https://www.ncbi.nlm.nih.gov/pubmed/29351191
http://dx.doi.org/10.3390/molecules23010195
_version_ 1783334835386843136
author Liu, E
Jian, Fangfang
author_facet Liu, E
Jian, Fangfang
author_sort Liu, E
collection PubMed
description Anionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physics are built on exploiting the regularity of atomic arrangements in crystal. Describing the crystalline order of solids is relatively straightforward. Here we report the crystal structure of an anionic water cluster polymer [(H(2)O)(18)(OH)(2)](n)(2n−) moiety that is stabilized by bis(2,2′-bipyridine) cupric chloride [Cu(bipy)(2)Cl](−) host.
format Online
Article
Text
id pubmed-6017829
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-60178292018-11-13 Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−) Liu, E Jian, Fangfang Molecules Communication Anionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physics are built on exploiting the regularity of atomic arrangements in crystal. Describing the crystalline order of solids is relatively straightforward. Here we report the crystal structure of an anionic water cluster polymer [(H(2)O)(18)(OH)(2)](n)(2n−) moiety that is stabilized by bis(2,2′-bipyridine) cupric chloride [Cu(bipy)(2)Cl](−) host. MDPI 2018-01-19 /pmc/articles/PMC6017829/ /pubmed/29351191 http://dx.doi.org/10.3390/molecules23010195 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Liu, E
Jian, Fangfang
Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title_full Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title_fullStr Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title_full_unstemmed Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title_short Anionic Water Cluster Polymers [(H(2)O)(18)(OH)(2)](n)(2n−) Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)(2)Cl](−)
title_sort anionic water cluster polymers [(h(2)o)(18)(oh)(2)](n)(2n−) is stabilized by bis(2,2′-bipyridine) cupric chloride [cu(bipy)(2)cl](−)
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017829/
https://www.ncbi.nlm.nih.gov/pubmed/29351191
http://dx.doi.org/10.3390/molecules23010195
work_keys_str_mv AT liue anionicwaterclusterpolymersh2o18oh2n2nisstabilizedbybis22bipyridinecupricchloridecubipy2cl
AT jianfangfang anionicwaterclusterpolymersh2o18oh2n2nisstabilizedbybis22bipyridinecupricchloridecubipy2cl

Ejemplares similares