Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers

Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacryla...

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Detalles Bibliográficos
Autores principales: Sun, Xing-Yu, Ren, Wei-Min, Liu, Si-Jie, Jia, Yin-Bao, Wang, Yi-Ming, Lu, Xiao-Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017872/
https://www.ncbi.nlm.nih.gov/pubmed/29466304
http://dx.doi.org/10.3390/molecules23020468
Descripción
Sumario:Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, “thiol-ene” click reaction and organocatalytic ring-opening polymerization of lactide.

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