Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers

Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacryla...

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Detalles Bibliográficos
Autores principales: Sun, Xing-Yu, Ren, Wei-Min, Liu, Si-Jie, Jia, Yin-Bao, Wang, Yi-Ming, Lu, Xiao-Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017872/
https://www.ncbi.nlm.nih.gov/pubmed/29466304
http://dx.doi.org/10.3390/molecules23020468
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author Sun, Xing-Yu
Ren, Wei-Min
Liu, Si-Jie
Jia, Yin-Bao
Wang, Yi-Ming
Lu, Xiao-Bing
author_facet Sun, Xing-Yu
Ren, Wei-Min
Liu, Si-Jie
Jia, Yin-Bao
Wang, Yi-Ming
Lu, Xiao-Bing
author_sort Sun, Xing-Yu
collection PubMed
description Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, “thiol-ene” click reaction and organocatalytic ring-opening polymerization of lactide.
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spelling pubmed-60178722018-11-13 Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers Sun, Xing-Yu Ren, Wei-Min Liu, Si-Jie Jia, Yin-Bao Wang, Yi-Ming Lu, Xiao-Bing Molecules Article Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, “thiol-ene” click reaction and organocatalytic ring-opening polymerization of lactide. MDPI 2018-02-21 /pmc/articles/PMC6017872/ /pubmed/29466304 http://dx.doi.org/10.3390/molecules23020468 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sun, Xing-Yu
Ren, Wei-Min
Liu, Si-Jie
Jia, Yin-Bao
Wang, Yi-Ming
Lu, Xiao-Bing
Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title_full Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title_fullStr Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title_full_unstemmed Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title_short Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers
title_sort tandem lewis pair polymerization and organocatalytic ring-opening polymerization for synthesizing block and brush copolymers
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017872/
https://www.ncbi.nlm.nih.gov/pubmed/29466304
http://dx.doi.org/10.3390/molecules23020468
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