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Electrical Conductivity Distribution in Detonating Benzotrifuroxane

Electrical conductivity profile behind the detonation front in the benzotrifuroxane (BTF) was measured using high-resolution technique. BTF is a peculiar high explosive which is completely hydrogen-free: its molecular formula is C(6)N(6)O(6). Results are compared with the conductivity distributions...

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Autores principales: Satonkina, Nataliya, Ershov, Alexander, Kashkarov, Alexey, Mikhaylov, Anatoly, Pruuel, Eduard, Rubtsov, Ivan, Spirin, Ivan, Titova, Victoria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018432/
https://www.ncbi.nlm.nih.gov/pubmed/29941986
http://dx.doi.org/10.1038/s41598-018-28028-2
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author Satonkina, Nataliya
Ershov, Alexander
Kashkarov, Alexey
Mikhaylov, Anatoly
Pruuel, Eduard
Rubtsov, Ivan
Spirin, Ivan
Titova, Victoria
author_facet Satonkina, Nataliya
Ershov, Alexander
Kashkarov, Alexey
Mikhaylov, Anatoly
Pruuel, Eduard
Rubtsov, Ivan
Spirin, Ivan
Titova, Victoria
author_sort Satonkina, Nataliya
collection PubMed
description Electrical conductivity profile behind the detonation front in the benzotrifuroxane (BTF) was measured using high-resolution technique. BTF is a peculiar high explosive which is completely hydrogen-free: its molecular formula is C(6)N(6)O(6). Results are compared with the conductivity distributions in detonating hexogen (RDX, C(3)H(6)N(6)O(6)) and triaminotrinitrobenzene based explosive (TATB, C(6)H(6)N(6)O(6)). The conductivity in BTF was found to be similar to that observed in the common explosives which contain hydrogen. Thus, the contribution of hydrogen (e.g., ions produced by the dissociation of water) in the conductivity is minor, both in the reaction zone and in the final detonation products. The characteristics of the conductivity profiles generally support the idea of contact conductivity through the connected structures of carbon particles formed in the detonation wave.
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spelling pubmed-60184322018-07-06 Electrical Conductivity Distribution in Detonating Benzotrifuroxane Satonkina, Nataliya Ershov, Alexander Kashkarov, Alexey Mikhaylov, Anatoly Pruuel, Eduard Rubtsov, Ivan Spirin, Ivan Titova, Victoria Sci Rep Article Electrical conductivity profile behind the detonation front in the benzotrifuroxane (BTF) was measured using high-resolution technique. BTF is a peculiar high explosive which is completely hydrogen-free: its molecular formula is C(6)N(6)O(6). Results are compared with the conductivity distributions in detonating hexogen (RDX, C(3)H(6)N(6)O(6)) and triaminotrinitrobenzene based explosive (TATB, C(6)H(6)N(6)O(6)). The conductivity in BTF was found to be similar to that observed in the common explosives which contain hydrogen. Thus, the contribution of hydrogen (e.g., ions produced by the dissociation of water) in the conductivity is minor, both in the reaction zone and in the final detonation products. The characteristics of the conductivity profiles generally support the idea of contact conductivity through the connected structures of carbon particles formed in the detonation wave. Nature Publishing Group UK 2018-06-25 /pmc/articles/PMC6018432/ /pubmed/29941986 http://dx.doi.org/10.1038/s41598-018-28028-2 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Satonkina, Nataliya
Ershov, Alexander
Kashkarov, Alexey
Mikhaylov, Anatoly
Pruuel, Eduard
Rubtsov, Ivan
Spirin, Ivan
Titova, Victoria
Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title_full Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title_fullStr Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title_full_unstemmed Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title_short Electrical Conductivity Distribution in Detonating Benzotrifuroxane
title_sort electrical conductivity distribution in detonating benzotrifuroxane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018432/
https://www.ncbi.nlm.nih.gov/pubmed/29941986
http://dx.doi.org/10.1038/s41598-018-28028-2
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