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A metal–organic framework immobilised iridium pincer complex

An iridium pincer complex has been immobilised in the metal–organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formati...

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Autores principales: Rimoldi, Martino, Nakamura, Akitake, Vermeulen, Nicolaas A., Henkelis, James J., Blackburn, Anthea K., Hupp, Joseph T., Stoddart, J. Fraser, Farha, Omar K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018438/
https://www.ncbi.nlm.nih.gov/pubmed/30155148
http://dx.doi.org/10.1039/c6sc01376g
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author Rimoldi, Martino
Nakamura, Akitake
Vermeulen, Nicolaas A.
Henkelis, James J.
Blackburn, Anthea K.
Hupp, Joseph T.
Stoddart, J. Fraser
Farha, Omar K.
author_facet Rimoldi, Martino
Nakamura, Akitake
Vermeulen, Nicolaas A.
Henkelis, James J.
Blackburn, Anthea K.
Hupp, Joseph T.
Stoddart, J. Fraser
Farha, Omar K.
author_sort Rimoldi, Martino
collection PubMed
description An iridium pincer complex has been immobilised in the metal–organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified NU-1000 is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside NU-1000 operated as an efficient heterogenous catalyst under flow conditions.
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spelling pubmed-60184382018-08-28 A metal–organic framework immobilised iridium pincer complex Rimoldi, Martino Nakamura, Akitake Vermeulen, Nicolaas A. Henkelis, James J. Blackburn, Anthea K. Hupp, Joseph T. Stoddart, J. Fraser Farha, Omar K. Chem Sci Chemistry An iridium pincer complex has been immobilised in the metal–organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified NU-1000 is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside NU-1000 operated as an efficient heterogenous catalyst under flow conditions. Royal Society of Chemistry 2016-08-01 2016-05-10 /pmc/articles/PMC6018438/ /pubmed/30155148 http://dx.doi.org/10.1039/c6sc01376g Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Rimoldi, Martino
Nakamura, Akitake
Vermeulen, Nicolaas A.
Henkelis, James J.
Blackburn, Anthea K.
Hupp, Joseph T.
Stoddart, J. Fraser
Farha, Omar K.
A metal–organic framework immobilised iridium pincer complex
title A metal–organic framework immobilised iridium pincer complex
title_full A metal–organic framework immobilised iridium pincer complex
title_fullStr A metal–organic framework immobilised iridium pincer complex
title_full_unstemmed A metal–organic framework immobilised iridium pincer complex
title_short A metal–organic framework immobilised iridium pincer complex
title_sort metal–organic framework immobilised iridium pincer complex
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018438/
https://www.ncbi.nlm.nih.gov/pubmed/30155148
http://dx.doi.org/10.1039/c6sc01376g
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