A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons

SAMs of a Y(iii) double-decker complex on ITO have been prepared and their electrical and optical properties explored, exhibiting three accessible stable redox states with characteristic absorption bands in the visible spectra, corresponding to three complementary colors (i.e., green, blue and red)....

Descripción completa

Detalles Bibliográficos
Autores principales: Alcón, I., Gonidec, M., Ajayakumar, M. R., Mas-Torrent, M., Veciana, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018459/
https://www.ncbi.nlm.nih.gov/pubmed/30155142
http://dx.doi.org/10.1039/c6sc00443a
_version_ 1783334954962255872
author Alcón, I.
Gonidec, M.
Ajayakumar, M. R.
Mas-Torrent, M.
Veciana, J.
author_facet Alcón, I.
Gonidec, M.
Ajayakumar, M. R.
Mas-Torrent, M.
Veciana, J.
author_sort Alcón, I.
collection PubMed
description SAMs of a Y(iii) double-decker complex on ITO have been prepared and their electrical and optical properties explored, exhibiting three accessible stable redox states with characteristic absorption bands in the visible spectra, corresponding to three complementary colors (i.e., green, blue and red). These absorption bands are exploited as output signals of this robust ternary electrochemical switch, behaving hence as an electrochromic molecular-based device.
format Online
Article
Text
id pubmed-6018459
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-60184592018-08-28 A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons Alcón, I. Gonidec, M. Ajayakumar, M. R. Mas-Torrent, M. Veciana, J. Chem Sci Chemistry SAMs of a Y(iii) double-decker complex on ITO have been prepared and their electrical and optical properties explored, exhibiting three accessible stable redox states with characteristic absorption bands in the visible spectra, corresponding to three complementary colors (i.e., green, blue and red). These absorption bands are exploited as output signals of this robust ternary electrochemical switch, behaving hence as an electrochromic molecular-based device. Royal Society of Chemistry 2016-08-01 2016-04-26 /pmc/articles/PMC6018459/ /pubmed/30155142 http://dx.doi.org/10.1039/c6sc00443a Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Alcón, I.
Gonidec, M.
Ajayakumar, M. R.
Mas-Torrent, M.
Veciana, J.
A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title_full A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title_fullStr A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title_full_unstemmed A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title_short A surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
title_sort surface confined yttrium(iii) bis-phthalocyaninato complex: a colourful switch controlled by electrons
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018459/
https://www.ncbi.nlm.nih.gov/pubmed/30155142
http://dx.doi.org/10.1039/c6sc00443a
work_keys_str_mv AT alconi asurfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT gonidecm asurfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT ajayakumarmr asurfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT mastorrentm asurfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT vecianaj asurfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT alconi surfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT gonidecm surfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT ajayakumarmr surfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT mastorrentm surfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons
AT vecianaj surfaceconfinedyttriumiiibisphthalocyaninatocomplexacolourfulswitchcontrolledbyelectrons

Ejemplares similares