Cargando…
The Si(2)H radical supported by two N-heterocyclic carbenes
Cyclic voltammetric studies of the hydridodisilicon(0,II) borate [(Idipp)(H)Si(II)[double bond, length as m-dash]Si(0)(Idipp)][B(Ar(F))(4)] (1H[B(Ar(F))(4)], Idipp = C[N(C(6)H(3)-2,6-iPr(2))CH](2), Ar(F) = C(6)H(3)-3,5-(CF(3))(2)) reveal a reversible one-electron reduction at a low redox potential (...
Autores principales: | Arz, Marius I., Schnakenburg, Gregor, Meyer, Andreas, Schiemann, Olav, Filippou, Alexander C. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018643/ https://www.ncbi.nlm.nih.gov/pubmed/30155147 http://dx.doi.org/10.1039/c6sc01569g |
Ejemplares similares
-
Silicon(i) chemistry: the NHC-stabilised silicon(i) halides Si(2)X(2)(Idipp)(2) (X = Br, I) and the disilicon(i)-iodido cation [Si(2)(I)(Idipp)(2)](+)
por: Arz, Marius I., et al.
Publicado: (2015) -
Recent advances in N-heterocyclic carbene-based radical catalysis
por: Ishii, Takuya, et al.
Publicado: (2020) -
C–H activation-annulation on the N-heterocyclic carbene platform
por: Dutta, Champak, et al.
Publicado: (2018) -
Selective multifunctionalization of N-heterocyclic carbene boranes via the intermediacy of boron-centered radicals
por: Li, Feng-Xing, et al.
Publicado: (2023) -
Actinide tetra-N-heterocyclic carbene ‘sandwiches’
por: DeJesus, Joseph F., et al.
Publicado: (2021)