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Heavier congeners of CO and CO(2) as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX(2) complexes (X = S, Se, Te)
In contrast to molecular CO and CO(2), their heavier mono- and dichalcogenide homologues, EX and EX(2) (E = Si, Ge, Sn, Pb; X = O, S, Se, Te), are important support materials (e.g., SiO(2)) and/or semiconductors (e.g., SiS(2)) and exist typically as insoluble crystalline or amorphous polymers under...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021755/ https://www.ncbi.nlm.nih.gov/pubmed/30034685 http://dx.doi.org/10.1039/c6sc01839d |