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Metal-free disproportionation of formic acid mediated by organoboranes

In the presence of dialkylboranes, formic acid can be converted to formaldehyde and methanol derivatives without the need for an external reductant. This reactivity, in which formates serve as the sole carbon and hydride sources, represents the first example of the disproportionation of formate anio...

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Detalles Bibliográficos
Autores principales: Chauvier, Clément, Thuéry, Pierre, Cantat, Thibault
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021958/
https://www.ncbi.nlm.nih.gov/pubmed/30034706
http://dx.doi.org/10.1039/c6sc01410k

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