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The reactivity of acyl chlorides towards sodium phosphaethynolate, Na(OCP): a mechanistic case study

The reaction of Na(OCP) with mesitoyl chloride delivers an ester functionalized 1,2,4-oxadiphosphole in a clean and P-atom economic way. The reaction mechanism has been elucidated by means of detailed NMR-spectroscopic, kinetic and computational studies. The initially formed acyl phosphaketene under...

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Detalles Bibliográficos
Autores principales:	Heift, Dominikus, Benkő, Zoltán, Suter, Riccardo, Verel, René, Grützmacher, Hansjörg
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024182/ https://www.ncbi.nlm.nih.gov/pubmed/30034752 http://dx.doi.org/10.1039/c6sc01269h

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