Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand

A dianionic tetrapodal pentadentate diborate ligand is introduced. This ligand forms a high spin neutral iron(ii) complex that reacts with a variety of organoazides to yield transient Fe(iii) imido radicals that are extremely potent hydrogen atom abstractors. The nature of these species is supported...

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Detalles Bibliográficos
Autores principales: Spasyuk, Denis M., Carpenter, Stephanie H., Kefalidis, Christos E., Piers, Warren E., Neidig, Michael L., Maron, Laurent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024611/
https://www.ncbi.nlm.nih.gov/pubmed/30034736
http://dx.doi.org/10.1039/c6sc01433j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024611/
https://www.ncbi.nlm.nih.gov/pubmed/30034736
http://dx.doi.org/10.1039/c6sc01433j

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