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Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand
A dianionic tetrapodal pentadentate diborate ligand is introduced. This ligand forms a high spin neutral iron(ii) complex that reacts with a variety of organoazides to yield transient Fe(iii) imido radicals that are extremely potent hydrogen atom abstractors. The nature of these species is supported...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024611/ https://www.ncbi.nlm.nih.gov/pubmed/30034736 http://dx.doi.org/10.1039/c6sc01433j |