Cargando…

Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties

Furan resin and fir powder pretreated by FeCl(3) and aqueous ammonia solution were used to fabricate α-Fe/Fe(3)C/woodceramic nanocomposite. The bands of the pretreated wood powder were characterized by Fourier transform infrared spectroscopy (FTIR). The structural characterization of the nanocomposi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhou, Weihong, Yu, Yunshui, Xiong, Xueliang, Zhou, Sicong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024902/
https://www.ncbi.nlm.nih.gov/pubmed/29794971
http://dx.doi.org/10.3390/ma11060878
_version_ 1783336160023543808
author Zhou, Weihong
Yu, Yunshui
Xiong, Xueliang
Zhou, Sicong
author_facet Zhou, Weihong
Yu, Yunshui
Xiong, Xueliang
Zhou, Sicong
author_sort Zhou, Weihong
collection PubMed
description Furan resin and fir powder pretreated by FeCl(3) and aqueous ammonia solution were used to fabricate α-Fe/Fe(3)C/woodceramic nanocomposite. The bands of the pretreated wood powder were characterized by Fourier transform infrared spectroscopy (FTIR). The structural characterization of the nanocomposites was performed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The microwave absorption of the nanocomposites was measured by a vector network analyzer in the range of 2–18 GHz. The mechanical properties of the composites were also investigated. XRD and SEM results show that the α-Fe and Fe(3)C nanoparticles are in-situ generated and disperse in the matrix of the woodceramic. The diameters of these nanoparticles increase with the increasing of concentration of FeCl(3) solution. The experimental results show that both the complex permittivity and the complex permeability of α-Fe/Fe(3)C/woodceramic nanocomposites increase as the concentration of FeCl(3) solution increases. The composites pretreated with 0.60 mol·L(−1) FeCl(3) have the best absorption properties. The maximum value of reflection loss (RL) at 3 mm thickness reaches −25.60 dB at 10.16 GHz and the bandwidth below −10 dB is about 2.5 GHz. Compared to woodceramic, the bending strength and compressive strength of α-Fe/Fe(3)C/woodceramic nanocomposites increase by 22.5% and 18.7% at most, respectively.
format Online
Article
Text
id pubmed-6024902
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-60249022018-07-09 Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties Zhou, Weihong Yu, Yunshui Xiong, Xueliang Zhou, Sicong Materials (Basel) Article Furan resin and fir powder pretreated by FeCl(3) and aqueous ammonia solution were used to fabricate α-Fe/Fe(3)C/woodceramic nanocomposite. The bands of the pretreated wood powder were characterized by Fourier transform infrared spectroscopy (FTIR). The structural characterization of the nanocomposites was performed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The microwave absorption of the nanocomposites was measured by a vector network analyzer in the range of 2–18 GHz. The mechanical properties of the composites were also investigated. XRD and SEM results show that the α-Fe and Fe(3)C nanoparticles are in-situ generated and disperse in the matrix of the woodceramic. The diameters of these nanoparticles increase with the increasing of concentration of FeCl(3) solution. The experimental results show that both the complex permittivity and the complex permeability of α-Fe/Fe(3)C/woodceramic nanocomposites increase as the concentration of FeCl(3) solution increases. The composites pretreated with 0.60 mol·L(−1) FeCl(3) have the best absorption properties. The maximum value of reflection loss (RL) at 3 mm thickness reaches −25.60 dB at 10.16 GHz and the bandwidth below −10 dB is about 2.5 GHz. Compared to woodceramic, the bending strength and compressive strength of α-Fe/Fe(3)C/woodceramic nanocomposites increase by 22.5% and 18.7% at most, respectively. MDPI 2018-05-24 /pmc/articles/PMC6024902/ /pubmed/29794971 http://dx.doi.org/10.3390/ma11060878 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhou, Weihong
Yu, Yunshui
Xiong, Xueliang
Zhou, Sicong
Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title_full Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title_fullStr Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title_full_unstemmed Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title_short Fabrication of α-Fe/Fe(3)C/Woodceramic Nanocomposite with Its Improved Microwave Absorption and Mechanical Properties
title_sort fabrication of α-fe/fe(3)c/woodceramic nanocomposite with its improved microwave absorption and mechanical properties
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024902/
https://www.ncbi.nlm.nih.gov/pubmed/29794971
http://dx.doi.org/10.3390/ma11060878
work_keys_str_mv AT zhouweihong fabricationofafefe3cwoodceramicnanocompositewithitsimprovedmicrowaveabsorptionandmechanicalproperties
AT yuyunshui fabricationofafefe3cwoodceramicnanocompositewithitsimprovedmicrowaveabsorptionandmechanicalproperties
AT xiongxueliang fabricationofafefe3cwoodceramicnanocompositewithitsimprovedmicrowaveabsorptionandmechanicalproperties
AT zhousicong fabricationofafefe3cwoodceramicnanocompositewithitsimprovedmicrowaveabsorptionandmechanicalproperties