Cargando…
Coarctate and Möbius: The Helical Orbitals of Allene and Other Cumulenes
[Image: see text] As brought to the attention of the community by Hendon et al. and noted by previous workers, the π orbitals of the equilibrium geometry odd-carbon (even number of double bonds = n) [n]cumulenes may be written in either rectilinear or helical form. We trace the origins and detailed...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6026781/ https://www.ncbi.nlm.nih.gov/pubmed/29974064 http://dx.doi.org/10.1021/acscentsci.8b00086 |