Cargando…
Mechanism of Chemical and Electrochemical N(2) Splitting by a Rhenium Pincer Complex
[Image: see text] A comprehensive mechanistic study of N(2) activation and splitting into terminal nitride ligands upon reduction of the rhenium dichloride complex [ReCl(2)(PNP)] is presented (PNP(–) = N(CH(2)CH(2)PtBu(2))(2)(–)). Low-temperature studies using chemical reductants enabled full charac...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6026835/ https://www.ncbi.nlm.nih.gov/pubmed/29856611 http://dx.doi.org/10.1021/jacs.8b03755 |