Cargando…
Mapping the Relationship between Glycosyl Acceptor Reactivity and Glycosylation Stereoselectivity
The reactivity of both coupling partners—the glycosyl donor and acceptor—is decisive for the outcome of a glycosylation reaction, in terms of both yield and stereoselectivity. Where the reactivity of glycosyl donors is well understood and can be controlled through manipulation of the functional/prot...
Autores principales: | van der Vorm, Stefan, van Hengst, Jacob M. A., Bakker, Marloes, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6032835/ https://www.ncbi.nlm.nih.gov/pubmed/29603532 http://dx.doi.org/10.1002/anie.201802899 |
Ejemplares similares
-
Mapping the effect of configuration and protecting group pattern on glycosyl acceptor reactivity
por: van Hengst, Jacob M. A., et al.
Publicado: (2023) -
The influence of acceptor nucleophilicity on the glycosylation reaction mechanism
por: van der Vorm, S., et al.
Publicado: (2017) -
Stereoselectivity of
Conformationally Restricted Glucosazide
Donors
por: van der Vorm, Stefan, et al.
Publicado: (2017) -
Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2‐Azidofuranoses, 2‐Fluorofuranoses and Methyl Furanosyl Uronates
por: van der Vorm, Stefan, et al.
Publicado: (2019) -
Defining the S(N)1 Side of Glycosylation
Reactions: Stereoselectivity of Glycopyranosyl Cations
por: Hansen, Thomas, et al.
Publicado: (2019)