Polycyclic Indoline‐Benzodiazepines through Electrophilic Additions of α‐Imino Carbenes to Tröger Bases

Polycyclic indoline‐benzodiazepines can be accessed through the intermolecular reaction of Tröger bases with N‐sulfonyl‐1,2,3‐triazoles. Under Rh(II) catalysis, α‐imino carbenes are generated and a subsequent cascade of [1,2]‐Stevens, Friedel–Crafts, Grob, and aminal formation reactions yield the po...

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Detalles Bibliográficos
Autores principales: Bosmani, Alessandro, Guarnieri‐Ibáñez, Alejandro, Goudedranche, Sébastien, Besnard, Céline, Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6033154/
https://www.ncbi.nlm.nih.gov/pubmed/29673027
http://dx.doi.org/10.1002/anie.201803756

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6033154/
https://www.ncbi.nlm.nih.gov/pubmed/29673027
http://dx.doi.org/10.1002/anie.201803756

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