Cargando…
Enantiodivergent Synthesis of Allenes by Point‐to‐Axial Chirality Transfer
An enantiodivergent method for the synthesis of multiply substituted allenes is described. Highly enantioenriched, point‐chiral boronic esters were synthesized by homologation of α‐seleno alkenyl boronic esters with lithiated carbamates and eliminated to form axially chiral allene products. By emplo...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6033179/ https://www.ncbi.nlm.nih.gov/pubmed/29719111 http://dx.doi.org/10.1002/anie.201804446 |