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Enantiodivergent Synthesis of Allenes by Point‐to‐Axial Chirality Transfer

An enantiodivergent method for the synthesis of multiply substituted allenes is described. Highly enantioenriched, point‐chiral boronic esters were synthesized by homologation of α‐seleno alkenyl boronic esters with lithiated carbamates and eliminated to form axially chiral allene products. By emplo...

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Detalles Bibliográficos
Autores principales:	Armstrong, Roly J., Nandakumar, Meganathan, Dias, Rafael M. P., Noble, Adam, Myers, Eddie L., Aggarwal, Varinder K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6033179/ https://www.ncbi.nlm.nih.gov/pubmed/29719111 http://dx.doi.org/10.1002/anie.201804446

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