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Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis
Most of the polyvalent organoiodine compounds derive from iodoarenes, which are released in stoichiometric amounts in any reaction mediated by λ(3)- or λ(5)-iodanes. In parallel to the development of solid-supported reagents or reactions catalytic in iodine, a third strategy has emerged to address t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037006/ https://www.ncbi.nlm.nih.gov/pubmed/30013678 http://dx.doi.org/10.3762/bjoc.14.128 |
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author | Grelier, Gwendal Darses, Benjamin Dauban, Philippe |
author_facet | Grelier, Gwendal Darses, Benjamin Dauban, Philippe |
author_sort | Grelier, Gwendal |
collection | PubMed |
description | Most of the polyvalent organoiodine compounds derive from iodoarenes, which are released in stoichiometric amounts in any reaction mediated by λ(3)- or λ(5)-iodanes. In parallel to the development of solid-supported reagents or reactions catalytic in iodine, a third strategy has emerged to address this issue in terms of sustainability. The atom-economy of transformations involving stoichiometric amounts of λ(3)- or λ(5)-iodanes, thus, has been improved by designing tandem reactions that allows for incorporating the aryl motif into the products through a subsequent one-pot nucleophilic addition or catalytic coupling reaction. This review summarizes the main achievements reported in this area. |
format | Online Article Text |
id | pubmed-6037006 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-60370062018-07-16 Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis Grelier, Gwendal Darses, Benjamin Dauban, Philippe Beilstein J Org Chem Review Most of the polyvalent organoiodine compounds derive from iodoarenes, which are released in stoichiometric amounts in any reaction mediated by λ(3)- or λ(5)-iodanes. In parallel to the development of solid-supported reagents or reactions catalytic in iodine, a third strategy has emerged to address this issue in terms of sustainability. The atom-economy of transformations involving stoichiometric amounts of λ(3)- or λ(5)-iodanes, thus, has been improved by designing tandem reactions that allows for incorporating the aryl motif into the products through a subsequent one-pot nucleophilic addition or catalytic coupling reaction. This review summarizes the main achievements reported in this area. Beilstein-Institut 2018-06-21 /pmc/articles/PMC6037006/ /pubmed/30013678 http://dx.doi.org/10.3762/bjoc.14.128 Text en Copyright © 2018, Grelier et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Review Grelier, Gwendal Darses, Benjamin Dauban, Philippe Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title | Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title_full | Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title_fullStr | Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title_full_unstemmed | Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title_short | Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
title_sort | hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037006/ https://www.ncbi.nlm.nih.gov/pubmed/30013678 http://dx.doi.org/10.3762/bjoc.14.128 |
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