Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic s...

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Autores principales: Yetra, Santhivardhana Reddy, Shen, Zhigao, Wang, Hui, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037017/
https://www.ncbi.nlm.nih.gov/pubmed/30013681
http://dx.doi.org/10.3762/bjoc.14.131
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author Yetra, Santhivardhana Reddy
Shen, Zhigao
Wang, Hui
Ackermann, Lutz
author_facet Yetra, Santhivardhana Reddy
Shen, Zhigao
Wang, Hui
Ackermann, Lutz
author_sort Yetra, Santhivardhana Reddy
collection PubMed
description Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic studies provided strong support for a facile organometallic C–H activation manifold.
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spelling pubmed-60370172018-07-16 Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical Yetra, Santhivardhana Reddy Shen, Zhigao Wang, Hui Ackermann, Lutz Beilstein J Org Chem Full Research Paper Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic studies provided strong support for a facile organometallic C–H activation manifold. Beilstein-Institut 2018-06-25 /pmc/articles/PMC6037017/ /pubmed/30013681 http://dx.doi.org/10.3762/bjoc.14.131 Text en Copyright © 2018, Yetra et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Yetra, Santhivardhana Reddy
Shen, Zhigao
Wang, Hui
Ackermann, Lutz
Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title_full Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title_fullStr Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title_full_unstemmed Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title_short Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical
title_sort thiocarbonyl-enabled ferrocene c–h nitrogenation by cobalt(iii) catalysis: thermal and mechanochemical
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037017/
https://www.ncbi.nlm.nih.gov/pubmed/30013681
http://dx.doi.org/10.3762/bjoc.14.131
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AT wanghui thiocarbonylenabledferrocenechnitrogenationbycobaltiiicatalysisthermalandmechanochemical
AT ackermannlutz thiocarbonylenabledferrocenechnitrogenationbycobaltiiicatalysisthermalandmechanochemical

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