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Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

Versatile C–H amidations of synthetically useful ferrocenes were accomplished by weakly-coordinating thiocarbonyl-assisted cobalt catalysis. Thus, carboxylates enabled ferrocene C–H nitrogenations with dioxazolones, featuring ample substrate scope and robust functional group tolerance. Mechanistic s...

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Detalles Bibliográficos
Autores principales: Yetra, Santhivardhana Reddy, Shen, Zhigao, Wang, Hui, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037017/
https://www.ncbi.nlm.nih.gov/pubmed/30013681
http://dx.doi.org/10.3762/bjoc.14.131