Methyl quantum tunneling in ionic liquid [DMIm][TFSI] facilitated by Bis(trifluoromethane)sulfonimide lithium salt

We probe, for the first time, quantum tunneling in the methyl groups of the ionic liquid [DMIm][TFSI] facilitated by the presence of Bis(trifluoromethane)sulfonimide lithium salt. The observation of tunneling is made possible by crystallization, rather than vitrification, of [DMIm][TFSI] at low temp...

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Detalles Bibliográficos
Autores principales: Do, Changwoo, Sun, Xiao-Guang, Jafta, Charl J., Dai, Sheng, Ohl, Michael, Mamontov, Eugene
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037680/
https://www.ncbi.nlm.nih.gov/pubmed/29985444
http://dx.doi.org/10.1038/s41598-018-28756-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037680/
https://www.ncbi.nlm.nih.gov/pubmed/29985444
http://dx.doi.org/10.1038/s41598-018-28756-5

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