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Methyl quantum tunneling in ionic liquid [DMIm][TFSI] facilitated by Bis(trifluoromethane)sulfonimide lithium salt
We probe, for the first time, quantum tunneling in the methyl groups of the ionic liquid [DMIm][TFSI] facilitated by the presence of Bis(trifluoromethane)sulfonimide lithium salt. The observation of tunneling is made possible by crystallization, rather than vitrification, of [DMIm][TFSI] at low temp...
Autores principales: | Do, Changwoo, Sun, Xiao-Guang, Jafta, Charl J., Dai, Sheng, Ohl, Michael, Mamontov, Eugene |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6037680/ https://www.ncbi.nlm.nih.gov/pubmed/29985444 http://dx.doi.org/10.1038/s41598-018-28756-5 |
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