Cargando…
Crystal structure of diethyl {2,2,2-trichloro-1-[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)-4-methylpentanamido]ethyl}phosphonate
In the title phosphorylated compound, C(20)H(26)Cl(3)N(2)O(6)P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129 Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3) Å. In the crystal, pairs of molecules are linked by N—H⋯O and weak C—H⋯O hydr...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038616/ https://www.ncbi.nlm.nih.gov/pubmed/30002885 http://dx.doi.org/10.1107/S2056989018008277 |
Sumario: | In the title phosphorylated compound, C(20)H(26)Cl(3)N(2)O(6)P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129 Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3) Å. In the crystal, pairs of molecules are linked by N—H⋯O and weak C—H⋯O hydrogen bonds involving the same acceptor atom, forming inversion dimers. In addition, π–π stacking interactions between the phthalimide groups, with a centroid–centroid distance of 3.7736 (13) Å, and further weak C—H⋯O hydrogen bonds connect the inversion dimers into columns along [0[Image: see text]1]. |
---|