Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

In the title compound, μ-di­phenyl­phosphido-μ-hydrido-bis­[bromido­(tri­phenyl­phosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt(2)Br(2)(C(12)H(10)P)H(C(18)H(15)P)(2)]·C(4)H(10)O or [Pt(2)(μ-H)(μ-PPh(2))Br(2)(PPh(3))(2)]·(C(2)H(5))(2)O, the Pt(II) atoms are coordinated in a distorted square...

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Detalles Bibliográficos
Autores principales: Ouis, Sakina, Rouag, Djamil Azzedine, Bendjeddou, Lamia, Bailly, Corinne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038636/
https://www.ncbi.nlm.nih.gov/pubmed/30002898
http://dx.doi.org/10.1107/S205698901800868X
Descripción
Sumario:In the title compound, μ-di­phenyl­phosphido-μ-hydrido-bis­[bromido­(tri­phenyl­phosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt(2)Br(2)(C(12)H(10)P)H(C(18)H(15)P)(2)]·C(4)H(10)O or [Pt(2)(μ-H)(μ-PPh(2))Br(2)(PPh(3))(2)]·(C(2)H(5))(2)O, the Pt(II) atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H⋯·O and C—H⋯π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each Pt(II) atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio.

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