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Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt(2)Br(2)(C(12)H(10)P)H(C(18)H(15)P)(2)]·C(4)H(10)O or [Pt(2)(μ-H)(μ-PPh(2))Br(2)(PPh(3))(2)]·(C(2)H(5))(2)O, the Pt(II) atoms are coordinated in a distorted square...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038636/ https://www.ncbi.nlm.nih.gov/pubmed/30002898 http://dx.doi.org/10.1107/S205698901800868X |
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author | Ouis, Sakina Rouag, Djamil Azzedine Bendjeddou, Lamia Bailly, Corinne |
author_facet | Ouis, Sakina Rouag, Djamil Azzedine Bendjeddou, Lamia Bailly, Corinne |
author_sort | Ouis, Sakina |
collection | PubMed |
description | In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt(2)Br(2)(C(12)H(10)P)H(C(18)H(15)P)(2)]·C(4)H(10)O or [Pt(2)(μ-H)(μ-PPh(2))Br(2)(PPh(3))(2)]·(C(2)H(5))(2)O, the Pt(II) atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H⋯·O and C—H⋯π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each Pt(II) atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio. |
format | Online Article Text |
id | pubmed-6038636 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-60386362018-07-12 Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands Ouis, Sakina Rouag, Djamil Azzedine Bendjeddou, Lamia Bailly, Corinne Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt(2)Br(2)(C(12)H(10)P)H(C(18)H(15)P)(2)]·C(4)H(10)O or [Pt(2)(μ-H)(μ-PPh(2))Br(2)(PPh(3))(2)]·(C(2)H(5))(2)O, the Pt(II) atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H⋯·O and C—H⋯π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each Pt(II) atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio. International Union of Crystallography 2018-06-19 /pmc/articles/PMC6038636/ /pubmed/30002898 http://dx.doi.org/10.1107/S205698901800868X Text en © Ouis et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Ouis, Sakina Rouag, Djamil Azzedine Bendjeddou, Lamia Bailly, Corinne Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title | Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title_full | Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title_fullStr | Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title_full_unstemmed | Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title_short | Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
title_sort | crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038636/ https://www.ncbi.nlm.nih.gov/pubmed/30002898 http://dx.doi.org/10.1107/S205698901800868X |
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