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Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one
The title compound, C(11)H(9)NO(3), contains an isoxazole and a hydroxybenzylidene ring, which are inclined to each another by 3.18 (8)°. There is an intramolecular C—H⋯O contact forming an S(7) ring. In the crystal, molecules stack head-to-tail in columns along the b-axis direction, linked by...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038640/ https://www.ncbi.nlm.nih.gov/pubmed/30002887 http://dx.doi.org/10.1107/S2056989018007867 |
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author | Zemamouche, Wissem Laroun, Rima Hamdouni, Noudjoud Brihi, Ouarda Boudjada, Ali Debache, Abdelmadjid |
author_facet | Zemamouche, Wissem Laroun, Rima Hamdouni, Noudjoud Brihi, Ouarda Boudjada, Ali Debache, Abdelmadjid |
author_sort | Zemamouche, Wissem |
collection | PubMed |
description | The title compound, C(11)H(9)NO(3), contains an isoxazole and a hydroxybenzylidene ring, which are inclined to each another by 3.18 (8)°. There is an intramolecular C—H⋯O contact forming an S(7) ring. In the crystal, molecules stack head-to-tail in columns along the b-axis direction, linked by offset π–π interactions [intercentroid distances of 3.676 (1) and 3.723 (1) Å]. The columns are linked by O—H⋯O and O—H⋯N hydrogen bonds, forming layers parallel to the ab plane. The layers are linked by C—H⋯O hydrogen bonds, forming a supramolecular three-dimensional framework. An analysis of the Hirshfeld surfaces points to the importance of the O—H⋯O and O—H⋯N hydrogen bonding in the packing mechanism of the crystal structure. |
format | Online Article Text |
id | pubmed-6038640 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-60386402018-07-12 Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one Zemamouche, Wissem Laroun, Rima Hamdouni, Noudjoud Brihi, Ouarda Boudjada, Ali Debache, Abdelmadjid Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(11)H(9)NO(3), contains an isoxazole and a hydroxybenzylidene ring, which are inclined to each another by 3.18 (8)°. There is an intramolecular C—H⋯O contact forming an S(7) ring. In the crystal, molecules stack head-to-tail in columns along the b-axis direction, linked by offset π–π interactions [intercentroid distances of 3.676 (1) and 3.723 (1) Å]. The columns are linked by O—H⋯O and O—H⋯N hydrogen bonds, forming layers parallel to the ab plane. The layers are linked by C—H⋯O hydrogen bonds, forming a supramolecular three-dimensional framework. An analysis of the Hirshfeld surfaces points to the importance of the O—H⋯O and O—H⋯N hydrogen bonding in the packing mechanism of the crystal structure. International Union of Crystallography 2018-06-08 /pmc/articles/PMC6038640/ /pubmed/30002887 http://dx.doi.org/10.1107/S2056989018007867 Text en © Zemamouche et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Zemamouche, Wissem Laroun, Rima Hamdouni, Noudjoud Brihi, Ouarda Boudjada, Ali Debache, Abdelmadjid Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title | Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title_full | Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title_fullStr | Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title_short | Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4H)-one |
title_sort | crystal structure and hirshfeld surface analysis of (z)-4-(4-hydroxybenzylidene)-3-methylisoxazol-5(4h)-one |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038640/ https://www.ncbi.nlm.nih.gov/pubmed/30002887 http://dx.doi.org/10.1107/S2056989018007867 |
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