Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one

The title compound, C(18)H(24)N(2)O, is the first example of a naphtho­quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol­ecular conformation is stabilized by an intra­molecular hydrogen bond between the amine and a carbon...

Descripción completa

Detalles Bibliográficos
Autores principales: Lamoureux, Guy, Alvarado-Rojas, Mónica, Pineda, Leslie W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038644/
https://www.ncbi.nlm.nih.gov/pubmed/30002897
http://dx.doi.org/10.1107/S2056989018008514
Descripción
Sumario:The title compound, C(18)H(24)N(2)O, is the first example of a naphtho­quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol­ecular conformation is stabilized by an intra­molecular hydrogen bond between the amine and a carbonyl group and by London attraction between the two tert-butyl groups. Only van der Waals inter­actions were identified in the crystal packing.

Ejemplares similares