Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one

The title compound, C(18)H(24)N(2)O, is the first example of a naphtho­quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol­ecular conformation is stabilized by an intra­molecular hydrogen bond between the amine and a carbon...

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Autores principales: Lamoureux, Guy, Alvarado-Rojas, Mónica, Pineda, Leslie W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038644/
https://www.ncbi.nlm.nih.gov/pubmed/30002897
http://dx.doi.org/10.1107/S2056989018008514
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author Lamoureux, Guy
Alvarado-Rojas, Mónica
Pineda, Leslie W.
author_facet Lamoureux, Guy
Alvarado-Rojas, Mónica
Pineda, Leslie W.
author_sort Lamoureux, Guy
collection PubMed
description The title compound, C(18)H(24)N(2)O, is the first example of a naphtho­quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol­ecular conformation is stabilized by an intra­molecular hydrogen bond between the amine and a carbonyl group and by London attraction between the two tert-butyl groups. Only van der Waals inter­actions were identified in the crystal packing.
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spelling pubmed-60386442018-07-12 Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one Lamoureux, Guy Alvarado-Rojas, Mónica Pineda, Leslie W. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(18)H(24)N(2)O, is the first example of a naphtho­quinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The mol­ecular conformation is stabilized by an intra­molecular hydrogen bond between the amine and a carbonyl group and by London attraction between the two tert-butyl groups. Only van der Waals inter­actions were identified in the crystal packing. International Union of Crystallography 2018-06-15 /pmc/articles/PMC6038644/ /pubmed/30002897 http://dx.doi.org/10.1107/S2056989018008514 Text en © Lamoureux et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Lamoureux, Guy
Alvarado-Rojas, Mónica
Pineda, Leslie W.
Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title_full Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title_fullStr Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title_full_unstemmed Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title_short Crystal structure of (E)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4H)-one
title_sort crystal structure of (e)-2-(tert-butyl­amino)-4-(tert-butyl­imino)­naphthalen-1(4h)-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038644/
https://www.ncbi.nlm.nih.gov/pubmed/30002897
http://dx.doi.org/10.1107/S2056989018008514
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