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Crystal structure of (E)-N’-[1-(4-amino­phen­yl)ethyl­idene]-2-hy­droxy-5-iodo­benzohydrazide methanol monosolvate

In the title compound, C(15)H(14)IN(3)O(2)·CH(3)OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol mol­ecule forms an O—H⋯O hydrogen bond to the hydrazi...

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Detalles Bibliográficos
Autores principales: Nguyen Tien, Cong, Le Thi Thu, Huong, Nguyen Van, Thin, Vu Quoc, Trung, Vu Quoc, Manh, Pham Chien, Thang, Van Meervelt, Luc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038649/
https://www.ncbi.nlm.nih.gov/pubmed/30002884
http://dx.doi.org/10.1107/S2056989018008204
Descripción
Sumario:In the title compound, C(15)H(14)IN(3)O(2)·CH(3)OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol mol­ecule forms an O—H⋯O hydrogen bond to the hydrazide O atom. In the crystal, chains of mol­ecules running along the c-axis direction are formed by O—H⋯O hydrogen bonds. Adjacent chains are linked through N—H⋯O hydrogen bonds and π–π stacking inter­actions. The inter­molecular inter­actions in the crystal packing were investigated using Hirshfeld surface analysis, which indicated that the most significant contacts are H⋯H (38.2%), followed by C⋯H/H⋯C (20.6%), O⋯H/H⋯O (11.1%) and I⋯H/H⋯I (9.7%).