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Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate
In the title compound, C(15)H(14)IN(3)O(2)·CH(3)OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol molecule forms an O—H⋯O hydrogen bond to the hydrazi...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038649/ https://www.ncbi.nlm.nih.gov/pubmed/30002884 http://dx.doi.org/10.1107/S2056989018008204 |
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author | Nguyen Tien, Cong Le Thi Thu, Huong Nguyen Van, Thin Vu Quoc, Trung Vu Quoc, Manh Pham Chien, Thang Van Meervelt, Luc |
author_facet | Nguyen Tien, Cong Le Thi Thu, Huong Nguyen Van, Thin Vu Quoc, Trung Vu Quoc, Manh Pham Chien, Thang Van Meervelt, Luc |
author_sort | Nguyen Tien, Cong |
collection | PubMed |
description | In the title compound, C(15)H(14)IN(3)O(2)·CH(3)OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol molecule forms an O—H⋯O hydrogen bond to the hydrazide O atom. In the crystal, chains of molecules running along the c-axis direction are formed by O—H⋯O hydrogen bonds. Adjacent chains are linked through N—H⋯O hydrogen bonds and π–π stacking interactions. The intermolecular interactions in the crystal packing were investigated using Hirshfeld surface analysis, which indicated that the most significant contacts are H⋯H (38.2%), followed by C⋯H/H⋯C (20.6%), O⋯H/H⋯O (11.1%) and I⋯H/H⋯I (9.7%). |
format | Online Article Text |
id | pubmed-6038649 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-60386492018-07-12 Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate Nguyen Tien, Cong Le Thi Thu, Huong Nguyen Van, Thin Vu Quoc, Trung Vu Quoc, Manh Pham Chien, Thang Van Meervelt, Luc Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(15)H(14)IN(3)O(2)·CH(3)OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol molecule forms an O—H⋯O hydrogen bond to the hydrazide O atom. In the crystal, chains of molecules running along the c-axis direction are formed by O—H⋯O hydrogen bonds. Adjacent chains are linked through N—H⋯O hydrogen bonds and π–π stacking interactions. The intermolecular interactions in the crystal packing were investigated using Hirshfeld surface analysis, which indicated that the most significant contacts are H⋯H (38.2%), followed by C⋯H/H⋯C (20.6%), O⋯H/H⋯O (11.1%) and I⋯H/H⋯I (9.7%). International Union of Crystallography 2018-06-08 /pmc/articles/PMC6038649/ /pubmed/30002884 http://dx.doi.org/10.1107/S2056989018008204 Text en © Nguyen Tien et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Nguyen Tien, Cong Le Thi Thu, Huong Nguyen Van, Thin Vu Quoc, Trung Vu Quoc, Manh Pham Chien, Thang Van Meervelt, Luc Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title | Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title_full | Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title_fullStr | Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title_full_unstemmed | Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title_short | Crystal structure of (E)-N’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
title_sort | crystal structure of (e)-n’-[1-(4-aminophenyl)ethylidene]-2-hydroxy-5-iodobenzohydrazide methanol monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038649/ https://www.ncbi.nlm.nih.gov/pubmed/30002884 http://dx.doi.org/10.1107/S2056989018008204 |
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