Pd(II)-Catalyzed Oxidative Aldehyde-sp(2)C–H Functionalization and Cyclization Using NHC with Mild Oxidant DMSO for the Selective Synthesis of Esters, Sugar-Based Analogues, and β-Hydroxy Chromanones: An (18)O-Labeling Study

[Image: see text] We assume formation of acyl-Pd(II)–N-heterocyclic-carbene (NHC) organometalics for diverse C–O/O–C and C–C/C–O coupling catalysis of direct functionalization and cyclization reactions. We report the first use of dimethyl sulfoxide (DMSO) as an oxidant under an inert atmosphere to O...

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Detalles Bibliográficos
Autores principales: Sarkar, Satinath, Laha, Radha M., Mitra, Rajendra N., Maiti, Dilip K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6044719/
https://www.ncbi.nlm.nih.gov/pubmed/30023497
http://dx.doi.org/10.1021/acsomega.6b00261

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6044719/
https://www.ncbi.nlm.nih.gov/pubmed/30023497
http://dx.doi.org/10.1021/acsomega.6b00261

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