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Pd(II)-Catalyzed Oxidative Aldehyde-sp(2)C–H Functionalization and Cyclization Using NHC with Mild Oxidant DMSO for the Selective Synthesis of Esters, Sugar-Based Analogues, and β-Hydroxy Chromanones: An (18)O-Labeling Study
[Image: see text] We assume formation of acyl-Pd(II)–N-heterocyclic-carbene (NHC) organometalics for diverse C–O/O–C and C–C/C–O coupling catalysis of direct functionalization and cyclization reactions. We report the first use of dimethyl sulfoxide (DMSO) as an oxidant under an inert atmosphere to O...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6044719/ https://www.ncbi.nlm.nih.gov/pubmed/30023497 http://dx.doi.org/10.1021/acsomega.6b00261 |