Nutty Carbon: Morphology Replicating Hard Carbon from Walnut Shell for Na Ion Battery Anode

[Image: see text] Efficient Na ion intercalation/deintercalation in the semigraphitic lattice of a hard carbon derived from the walnut shell is demonstrated. High-temperature (1000 °C) pyrolysis of walnut shells under an inert atmosphere yields a hard carbon with a low surface area (59 m(2) g(–1)) and a large interplanar c axis separation of 0.39–0.36 nm as compared to 0.32 nm for graphite, suitable for Na ion intercalation/deintercalation. A stable reversible capacity of 257 mAh g(–1) is observed at a current density of 50 mA g(–1) for such nutshell-derived carbon (NDC) with an impressive rate performance. No loss of electrochemical performance is observed for high current cycling (100 mA g(–1) → 2 A g(–1) → 100 mA g(–1)). Additionally, the NDC shows remarkably stable electrochemical performance up to 300 charge–discharge cycles at 100 mA g(–1) with a minimal drop in capacity.