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Multifunctional Bismuth Oxychloride/Mesoporous Silica Composites for Photocatalysis, Antibacterial Test, and Simultaneous Stripping Analysis of Heavy Metals
[Image: see text] The increasing complexity of environmental pollution nowadays poses a severe threat to the public health, which attracts considerable attentions in searching for nanomaterials of multiproperty. In this study, mesoporous silica of KIT-6-encapsulated bismuth oxychloride (BiOCl), an i...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6044972/ https://www.ncbi.nlm.nih.gov/pubmed/30023795 http://dx.doi.org/10.1021/acsomega.7b01590 |
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author | Song, Yiyan Jiang, Huijun Bi, Hongkai Zhong, Guowei Chen, Jin Wu, Yuan Wei, Wei |
author_facet | Song, Yiyan Jiang, Huijun Bi, Hongkai Zhong, Guowei Chen, Jin Wu, Yuan Wei, Wei |
author_sort | Song, Yiyan |
collection | PubMed |
description | [Image: see text] The increasing complexity of environmental pollution nowadays poses a severe threat to the public health, which attracts considerable attentions in searching for nanomaterials of multiproperty. In this study, mesoporous silica of KIT-6-encapsulated bismuth oxychloride (BiOCl), an intrinsically multifunctional material exhibiting bunched structure in the composites, are facilely prepared under hydrothermal conditions. Subsequently, the produced materials of multifunctionality were applied for photocatalysis, antibacterial test, and simultaneous determination of heavy metals including lead and cadmium. A combination of physiochemical characterizations have revealed that the BiOCl–KIT-6 composites exhibit enlarged yet refined surface morphology contributing to the improved photocatalytic ability with a band gap of 3.06 eV at a molecular ratio of 8Bi–Si. Moreover, the antibacterial activities of our BiOCl–KIT-6 composites were explored, and possible antimicrobial mechanism related to the production of reactive oxygen species was discussed. Furthermore, a sensitive electrochemical determination of heavy metals of lead and cadmium using square-wave anodic stripping voltammetry was also achieved. The composites-modified glassy carbon electrode displays a linear range of calibration curve from 0.2 to 300 μg/L with a detection limit of 0.05 μg/L (Pb(2+)) and 0.06 μg/L (Cd(2+)), respectively. |
format | Online Article Text |
id | pubmed-6044972 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-60449722018-07-16 Multifunctional Bismuth Oxychloride/Mesoporous Silica Composites for Photocatalysis, Antibacterial Test, and Simultaneous Stripping Analysis of Heavy Metals Song, Yiyan Jiang, Huijun Bi, Hongkai Zhong, Guowei Chen, Jin Wu, Yuan Wei, Wei ACS Omega [Image: see text] The increasing complexity of environmental pollution nowadays poses a severe threat to the public health, which attracts considerable attentions in searching for nanomaterials of multiproperty. In this study, mesoporous silica of KIT-6-encapsulated bismuth oxychloride (BiOCl), an intrinsically multifunctional material exhibiting bunched structure in the composites, are facilely prepared under hydrothermal conditions. Subsequently, the produced materials of multifunctionality were applied for photocatalysis, antibacterial test, and simultaneous determination of heavy metals including lead and cadmium. A combination of physiochemical characterizations have revealed that the BiOCl–KIT-6 composites exhibit enlarged yet refined surface morphology contributing to the improved photocatalytic ability with a band gap of 3.06 eV at a molecular ratio of 8Bi–Si. Moreover, the antibacterial activities of our BiOCl–KIT-6 composites were explored, and possible antimicrobial mechanism related to the production of reactive oxygen species was discussed. Furthermore, a sensitive electrochemical determination of heavy metals of lead and cadmium using square-wave anodic stripping voltammetry was also achieved. The composites-modified glassy carbon electrode displays a linear range of calibration curve from 0.2 to 300 μg/L with a detection limit of 0.05 μg/L (Pb(2+)) and 0.06 μg/L (Cd(2+)), respectively. American Chemical Society 2018-01-25 /pmc/articles/PMC6044972/ /pubmed/30023795 http://dx.doi.org/10.1021/acsomega.7b01590 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Song, Yiyan Jiang, Huijun Bi, Hongkai Zhong, Guowei Chen, Jin Wu, Yuan Wei, Wei Multifunctional Bismuth Oxychloride/Mesoporous Silica Composites for Photocatalysis, Antibacterial Test, and Simultaneous Stripping Analysis of Heavy Metals |
title | Multifunctional Bismuth Oxychloride/Mesoporous Silica
Composites for Photocatalysis, Antibacterial Test, and Simultaneous
Stripping Analysis of Heavy Metals |
title_full | Multifunctional Bismuth Oxychloride/Mesoporous Silica
Composites for Photocatalysis, Antibacterial Test, and Simultaneous
Stripping Analysis of Heavy Metals |
title_fullStr | Multifunctional Bismuth Oxychloride/Mesoporous Silica
Composites for Photocatalysis, Antibacterial Test, and Simultaneous
Stripping Analysis of Heavy Metals |
title_full_unstemmed | Multifunctional Bismuth Oxychloride/Mesoporous Silica
Composites for Photocatalysis, Antibacterial Test, and Simultaneous
Stripping Analysis of Heavy Metals |
title_short | Multifunctional Bismuth Oxychloride/Mesoporous Silica
Composites for Photocatalysis, Antibacterial Test, and Simultaneous
Stripping Analysis of Heavy Metals |
title_sort | multifunctional bismuth oxychloride/mesoporous silica
composites for photocatalysis, antibacterial test, and simultaneous
stripping analysis of heavy metals |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6044972/ https://www.ncbi.nlm.nih.gov/pubmed/30023795 http://dx.doi.org/10.1021/acsomega.7b01590 |
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