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The 3(rd) degree of biomimetism: associating the cavity effect, Zn(II) coordination and internal base assistance for guest binding and activation
The synthesis and characterization of a resorcinarene-based tetra(imidazole) ligand is reported. The properties of the corresponding Zn(II) complex are studied in depth, notably by NMR spectroscopy. In MeCN, acid–base titration reveals that one out of the four imidazole arms is hemi-labile and can b...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6048688/ https://www.ncbi.nlm.nih.gov/pubmed/30079177 http://dx.doi.org/10.1039/c8sc01129j |