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Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
An in-depth experimental and theoretical study of the substituent exchange reaction of silylium ions is presented. Apart from the substitution pattern at the silicon atom, the selectivity of this process is predominantly influenced by the counteranion, which is introduced with the trityl salt in the...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6048699/ https://www.ncbi.nlm.nih.gov/pubmed/30061992 http://dx.doi.org/10.1039/c8sc01833b |