Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

Numerous reactions are catalyzed by complexes of metals (M) with N-heterocyclic carbene (NHC) ligands, typically in the presence of oxygen bases, which significantly shape the performance. It is generally accepted that bases are required for either substrate activation (exemplified by transmetallati...

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Detalles Bibliográficos
Autores principales: Chernyshev, Victor M., Khazipov, Oleg V., Shevchenko, Maxim A., Chernenko, Andrey Yu., Astakhov, Alexander V., Eremin, Dmitry B., Pasyukov, Dmitry V., Kashin, Alexey S., Ananikov, Valentine P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6048739/
https://www.ncbi.nlm.nih.gov/pubmed/30061988
http://dx.doi.org/10.1039/c8sc01353e

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