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Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions

A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), lead...

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Autores principales: Moussa, Mehdi Elsayed, Welsch, Stefan, Lochner, Matthias, Peresypkina, Eugenia V., Virovets, Alexander V., Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6049892/
https://www.ncbi.nlm.nih.gov/pubmed/30034271
http://dx.doi.org/10.1002/ejic.201800112
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author Moussa, Mehdi Elsayed
Welsch, Stefan
Lochner, Matthias
Peresypkina, Eugenia V.
Virovets, Alexander V.
Scheer, Manfred
author_facet Moussa, Mehdi Elsayed
Welsch, Stefan
Lochner, Matthias
Peresypkina, Eugenia V.
Virovets, Alexander V.
Scheer, Manfred
author_sort Moussa, Mehdi Elsayed
collection PubMed
description A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[BF(4)](4n) (4) and [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[PF(6)](4n) (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu(2)Cl(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(12)H(10)N(2))](n) (6) and [Cu(2)Br(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(10)H(8)N(2))](n) (7).
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spelling pubmed-60498922018-07-20 Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions Moussa, Mehdi Elsayed Welsch, Stefan Lochner, Matthias Peresypkina, Eugenia V. Virovets, Alexander V. Scheer, Manfred Eur J Inorg Chem Full Papers A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[BF(4)](4n) (4) and [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[PF(6)](4n) (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu(2)Cl(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(12)H(10)N(2))](n) (6) and [Cu(2)Br(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(10)H(8)N(2))](n) (7). John Wiley and Sons Inc. 2018-06-11 2018-06-22 /pmc/articles/PMC6049892/ /pubmed/30034271 http://dx.doi.org/10.1002/ejic.201800112 Text en © 2018 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Moussa, Mehdi Elsayed
Welsch, Stefan
Lochner, Matthias
Peresypkina, Eugenia V.
Virovets, Alexander V.
Scheer, Manfred
Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title_full Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title_fullStr Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title_full_unstemmed Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title_short Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
title_sort organometallic–organic hybrid polymers assembled from pentaphosphaferrocene, bipyridyl linkers, and cu(i) ions
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6049892/
https://www.ncbi.nlm.nih.gov/pubmed/30034271
http://dx.doi.org/10.1002/ejic.201800112
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