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Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions
A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), lead...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6049892/ https://www.ncbi.nlm.nih.gov/pubmed/30034271 http://dx.doi.org/10.1002/ejic.201800112 |
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author | Moussa, Mehdi Elsayed Welsch, Stefan Lochner, Matthias Peresypkina, Eugenia V. Virovets, Alexander V. Scheer, Manfred |
author_facet | Moussa, Mehdi Elsayed Welsch, Stefan Lochner, Matthias Peresypkina, Eugenia V. Virovets, Alexander V. Scheer, Manfred |
author_sort | Moussa, Mehdi Elsayed |
collection | PubMed |
description | A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[BF(4)](4n) (4) and [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[PF(6)](4n) (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu(2)Cl(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(12)H(10)N(2))](n) (6) and [Cu(2)Br(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(10)H(8)N(2))](n) (7). |
format | Online Article Text |
id | pubmed-6049892 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-60498922018-07-20 Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions Moussa, Mehdi Elsayed Welsch, Stefan Lochner, Matthias Peresypkina, Eugenia V. Virovets, Alexander V. Scheer, Manfred Eur J Inorg Chem Full Papers A multicomponent approach of the P(n) ligand complex [Cp*Fe(η(5)‐P(5))] (1: Cp* = η(5)‐C(5)Me(5)) with the ditopic organic linkers 4,4′‐bipyridine (2) or trans‐1,2‐di(pyridine‐4‐yl)ethene (3) in the presence of Cu(I) salts of the anions [BF(4)](–) and [PF(6)](–) or the coordinating anion Br(–), leads to the formation of four novel organometallic–organic hybrid polymers: the cationic 1D polymeric compounds [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[BF(4)](4n) (4) and [Cu(4){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(2)(µ,η(1:1)‐C(10)H(8)N(2))(4)(CH(3)CN)(4)](n)[PF(6)](4n) (5) as well as the unique neutral threefold 2D → 2D interpenetrated networks [Cu(2)Cl(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(12)H(10)N(2))](n) (6) and [Cu(2)Br(2){Cp*Fe(µ(3),η(5:1:1)‐P(5))}(µ,η(1:1)‐C(10)H(8)N(2))](n) (7). John Wiley and Sons Inc. 2018-06-11 2018-06-22 /pmc/articles/PMC6049892/ /pubmed/30034271 http://dx.doi.org/10.1002/ejic.201800112 Text en © 2018 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Full Papers Moussa, Mehdi Elsayed Welsch, Stefan Lochner, Matthias Peresypkina, Eugenia V. Virovets, Alexander V. Scheer, Manfred Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title | Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title_full | Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title_fullStr | Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title_full_unstemmed | Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title_short | Organometallic–Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and Cu(I) Ions |
title_sort | organometallic–organic hybrid polymers assembled from pentaphosphaferrocene, bipyridyl linkers, and cu(i) ions |
topic | Full Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6049892/ https://www.ncbi.nlm.nih.gov/pubmed/30034271 http://dx.doi.org/10.1002/ejic.201800112 |
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