Facile synthesis of polycyclic metallaarynes

Metalla-analogs of polycyclic arynes represent an interesting class of metallaaromatics with a formal M[triple bond, length as m-dash]C bond within the ring. The first examples of a bicyclic β-metallaaryne and tricyclic metallaarynes, including a metallaanthracyne and a metallaphenanthryne, were obt...

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Autores principales: Ruan, Wenqing, Leung, Tsz-Fai, Shi, Chuan, Lee, Ka Ho, Sung, Herman H. Y., Williams, Ian D., Lin, Zhenyang, Jia, Guochen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050526/
https://www.ncbi.nlm.nih.gov/pubmed/30079214
http://dx.doi.org/10.1039/c8sc02086h
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author Ruan, Wenqing
Leung, Tsz-Fai
Shi, Chuan
Lee, Ka Ho
Sung, Herman H. Y.
Williams, Ian D.
Lin, Zhenyang
Jia, Guochen
author_facet Ruan, Wenqing
Leung, Tsz-Fai
Shi, Chuan
Lee, Ka Ho
Sung, Herman H. Y.
Williams, Ian D.
Lin, Zhenyang
Jia, Guochen
author_sort Ruan, Wenqing
collection PubMed
description Metalla-analogs of polycyclic arynes represent an interesting class of metallaaromatics with a formal M[triple bond, length as m-dash]C bond within the ring. The first examples of a bicyclic β-metallaaryne and tricyclic metallaarynes, including a metallaanthracyne and a metallaphenanthryne, were obtained in good yields by reactions of OsCl(2)(PPh(3))(3) with alkyne-functionalized phosphorus ylides.
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spelling pubmed-60505262018-08-03 Facile synthesis of polycyclic metallaarynes Ruan, Wenqing Leung, Tsz-Fai Shi, Chuan Lee, Ka Ho Sung, Herman H. Y. Williams, Ian D. Lin, Zhenyang Jia, Guochen Chem Sci Chemistry Metalla-analogs of polycyclic arynes represent an interesting class of metallaaromatics with a formal M[triple bond, length as m-dash]C bond within the ring. The first examples of a bicyclic β-metallaaryne and tricyclic metallaarynes, including a metallaanthracyne and a metallaphenanthryne, were obtained in good yields by reactions of OsCl(2)(PPh(3))(3) with alkyne-functionalized phosphorus ylides. Royal Society of Chemistry 2018-06-19 /pmc/articles/PMC6050526/ /pubmed/30079214 http://dx.doi.org/10.1039/c8sc02086h Text en This journal is © The Royal Society of Chemistry 2018 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Ruan, Wenqing
Leung, Tsz-Fai
Shi, Chuan
Lee, Ka Ho
Sung, Herman H. Y.
Williams, Ian D.
Lin, Zhenyang
Jia, Guochen
Facile synthesis of polycyclic metallaarynes
title Facile synthesis of polycyclic metallaarynes
title_full Facile synthesis of polycyclic metallaarynes
title_fullStr Facile synthesis of polycyclic metallaarynes
title_full_unstemmed Facile synthesis of polycyclic metallaarynes
title_short Facile synthesis of polycyclic metallaarynes
title_sort facile synthesis of polycyclic metallaarynes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050526/
https://www.ncbi.nlm.nih.gov/pubmed/30079214
http://dx.doi.org/10.1039/c8sc02086h
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