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Chiral Brønsted acid-catalyzed intramolecular S(N)2′ reaction for enantioselective construction of a quaternary stereogenic center

An enantioselective intramolecular anti-S(N)2′ cyclization reaction for the construction of a quaternary stereogenic center was accomplished through the activation of the leaving group using a binaphthol-derived phosphoramide as the chiral Brønsted acid catalyst. The present allylic substitution rea...

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Detalles Bibliográficos
Autores principales:	Shimizu, Masahiro, Kikuchi, Jun, Kondoh, Azusa, Terada, Masahiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050593/ https://www.ncbi.nlm.nih.gov/pubmed/30079184 http://dx.doi.org/10.1039/c8sc01942h

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