Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple

A series of cationic complexes involving a pnictogen(iii) (Pn = P, As, Sb) centre and the tetradentate ligand tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt(3)) have been synthesized and comprehensively characterized. Oxidation of [P(BIMEt(3))](3+) with XeF(2) provides access to [PF(2)(BIMEt(3...

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Autores principales: Swidan, Ala'aeddeen, Suter, Riccardo, Macdonald, Charles L. B., Burford, Neil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050602/
https://www.ncbi.nlm.nih.gov/pubmed/30079196
http://dx.doi.org/10.1039/c8sc01682h
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author Swidan, Ala'aeddeen
Suter, Riccardo
Macdonald, Charles L. B.
Burford, Neil
author_facet Swidan, Ala'aeddeen
Suter, Riccardo
Macdonald, Charles L. B.
Burford, Neil
author_sort Swidan, Ala'aeddeen
collection PubMed
description A series of cationic complexes involving a pnictogen(iii) (Pn = P, As, Sb) centre and the tetradentate ligand tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt(3)) have been synthesized and comprehensively characterized. Oxidation of [P(BIMEt(3))](3+) with XeF(2) provides access to [PF(2)(BIMEt(3))](3+) representing the first structurally characterized example of a phosphorus(v) centred trication.
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spelling pubmed-60506022018-08-03 Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple Swidan, Ala'aeddeen Suter, Riccardo Macdonald, Charles L. B. Burford, Neil Chem Sci Chemistry A series of cationic complexes involving a pnictogen(iii) (Pn = P, As, Sb) centre and the tetradentate ligand tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt(3)) have been synthesized and comprehensively characterized. Oxidation of [P(BIMEt(3))](3+) with XeF(2) provides access to [PF(2)(BIMEt(3))](3+) representing the first structurally characterized example of a phosphorus(v) centred trication. Royal Society of Chemistry 2018-06-19 /pmc/articles/PMC6050602/ /pubmed/30079196 http://dx.doi.org/10.1039/c8sc01682h Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Swidan, Ala'aeddeen
Suter, Riccardo
Macdonald, Charles L. B.
Burford, Neil
Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title_full Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title_fullStr Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title_full_unstemmed Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title_short Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
title_sort tris(benzoimidazol)amine (l) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [lp](3+)/[lpf(2)](3+) redox couple
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050602/
https://www.ncbi.nlm.nih.gov/pubmed/30079196
http://dx.doi.org/10.1039/c8sc01682h
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