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Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP](3+)/[LPF(2)](3+) redox couple
A series of cationic complexes involving a pnictogen(iii) (Pn = P, As, Sb) centre and the tetradentate ligand tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt(3)) have been synthesized and comprehensively characterized. Oxidation of [P(BIMEt(3))](3+) with XeF(2) provides access to [PF(2)(BIMEt(3...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050602/ https://www.ncbi.nlm.nih.gov/pubmed/30079196 http://dx.doi.org/10.1039/c8sc01682h |