Deciphering the mechanism of O(2) reduction with electronically tunable non-heme iron enzyme model complexes

A homologous series of electronically tuned 2,2′,2′′-nitrilotris(N-arylacetamide) pre-ligands (H(3)L(R)) were prepared (R = NO(2), CN, CF(3), F, Cl, Br, Et, Me, H, OMe, NMe(2)) and some of their corresponding Fe and Zn species synthesized. The iron complexes react rapidly with O(2), the final produc...

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Detalles Bibliográficos
Autores principales: Surendhran, Roshaan, D'Arpino, Alexander A., Sciscent, Bao Y., Cannella, Anthony F., Friedman, Alan E., MacMillan, Samantha N., Gupta, Rupal, Lacy, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050603/
https://www.ncbi.nlm.nih.gov/pubmed/30079187
http://dx.doi.org/10.1039/c8sc01621f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050603/
https://www.ncbi.nlm.nih.gov/pubmed/30079187
http://dx.doi.org/10.1039/c8sc01621f

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