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Deciphering the mechanism of O(2) reduction with electronically tunable non-heme iron enzyme model complexes
A homologous series of electronically tuned 2,2′,2′′-nitrilotris(N-arylacetamide) pre-ligands (H(3)L(R)) were prepared (R = NO(2), CN, CF(3), F, Cl, Br, Et, Me, H, OMe, NMe(2)) and some of their corresponding Fe and Zn species synthesized. The iron complexes react rapidly with O(2), the final produc...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050603/ https://www.ncbi.nlm.nih.gov/pubmed/30079187 http://dx.doi.org/10.1039/c8sc01621f |