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11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers

The enhancement of interfacial charge collection efficiency using buffer layers is a cost‐effective way to improve the performance of organic photovoltaic devices (OPVs) because they are often universally applicable regardless of the active materials. However, the availability of high‐performance bu...

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Autores principales: Aqoma, Havid, Park, Sujung, Park, Hye‐Yun, Hadmojo, Wisnu Tantyo, Oh, Seung‐Hwan, Nho, Sungho, Kim, Do Hui, Seo, Jeonghoon, Park, Sungmin, Ryu, Du Yeol, Cho, Shinuk, Jang, Sung‐Yeon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6051392/
https://www.ncbi.nlm.nih.gov/pubmed/30027029
http://dx.doi.org/10.1002/advs.201700858
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author Aqoma, Havid
Park, Sujung
Park, Hye‐Yun
Hadmojo, Wisnu Tantyo
Oh, Seung‐Hwan
Nho, Sungho
Kim, Do Hui
Seo, Jeonghoon
Park, Sungmin
Ryu, Du Yeol
Cho, Shinuk
Jang, Sung‐Yeon
author_facet Aqoma, Havid
Park, Sujung
Park, Hye‐Yun
Hadmojo, Wisnu Tantyo
Oh, Seung‐Hwan
Nho, Sungho
Kim, Do Hui
Seo, Jeonghoon
Park, Sungmin
Ryu, Du Yeol
Cho, Shinuk
Jang, Sung‐Yeon
author_sort Aqoma, Havid
collection PubMed
description The enhancement of interfacial charge collection efficiency using buffer layers is a cost‐effective way to improve the performance of organic photovoltaic devices (OPVs) because they are often universally applicable regardless of the active materials. However, the availability of high‐performance buffer materials, which are solution‐processable at low temperature, are limited and they often require burdensome additional surface modifications. Herein, high‐performance ZnO based electron transporting layers (ETLs) for OPVs are developed with a novel g‐ray‐assisted solution process. Through careful formulation of the ZnO precursor and g‐ray irradiation, the pre‐formation of ZnO nanoparticles occurs in the precursor solutions, which enables the preparation of high quality ZnO films. The g‐ray assisted ZnO (ZnO‐G) films possess a remarkably low defect density compared to the conventionally prepared ZnO films. The low‐defect ZnO‐G films can improve charge extraction efficiency of ETL without any additional treatment. The power conversion efficiency (PCE) of the device using the ZnO‐G ETLs is 11.09% with an open‐circuit voltage (V (OC)), short‐circuit current density ( J (SC)), and fill factor (FF) of 0.80 V, 19.54 mA cm(‐2), and 0.71, respectively, which is one of the best values among widely studied poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b;4,5‐b′]dithiophene‐2,6‐diyl‐alt‐(4‐(2‐ethylhexyl)‐3‐fluorothieno[3,4‐b]thiophene‐)‐2‐carboxylate‐2‐6‐diyl)]: [6,6]‐phenyl‐C(71)‐butyric acid methyl ester (PTB7‐Th:PC(71)BM)‐based devices.
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spelling pubmed-60513922018-07-19 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers Aqoma, Havid Park, Sujung Park, Hye‐Yun Hadmojo, Wisnu Tantyo Oh, Seung‐Hwan Nho, Sungho Kim, Do Hui Seo, Jeonghoon Park, Sungmin Ryu, Du Yeol Cho, Shinuk Jang, Sung‐Yeon Adv Sci (Weinh) Full Papers The enhancement of interfacial charge collection efficiency using buffer layers is a cost‐effective way to improve the performance of organic photovoltaic devices (OPVs) because they are often universally applicable regardless of the active materials. However, the availability of high‐performance buffer materials, which are solution‐processable at low temperature, are limited and they often require burdensome additional surface modifications. Herein, high‐performance ZnO based electron transporting layers (ETLs) for OPVs are developed with a novel g‐ray‐assisted solution process. Through careful formulation of the ZnO precursor and g‐ray irradiation, the pre‐formation of ZnO nanoparticles occurs in the precursor solutions, which enables the preparation of high quality ZnO films. The g‐ray assisted ZnO (ZnO‐G) films possess a remarkably low defect density compared to the conventionally prepared ZnO films. The low‐defect ZnO‐G films can improve charge extraction efficiency of ETL without any additional treatment. The power conversion efficiency (PCE) of the device using the ZnO‐G ETLs is 11.09% with an open‐circuit voltage (V (OC)), short‐circuit current density ( J (SC)), and fill factor (FF) of 0.80 V, 19.54 mA cm(‐2), and 0.71, respectively, which is one of the best values among widely studied poly[4,8‐bis(5‐(2‐ethylhexyl)thiophen‐2‐yl)benzo[1,2‐b;4,5‐b′]dithiophene‐2,6‐diyl‐alt‐(4‐(2‐ethylhexyl)‐3‐fluorothieno[3,4‐b]thiophene‐)‐2‐carboxylate‐2‐6‐diyl)]: [6,6]‐phenyl‐C(71)‐butyric acid methyl ester (PTB7‐Th:PC(71)BM)‐based devices. John Wiley and Sons Inc. 2018-05-21 /pmc/articles/PMC6051392/ /pubmed/30027029 http://dx.doi.org/10.1002/advs.201700858 Text en © 2018 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Aqoma, Havid
Park, Sujung
Park, Hye‐Yun
Hadmojo, Wisnu Tantyo
Oh, Seung‐Hwan
Nho, Sungho
Kim, Do Hui
Seo, Jeonghoon
Park, Sungmin
Ryu, Du Yeol
Cho, Shinuk
Jang, Sung‐Yeon
11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title_full 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title_fullStr 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title_full_unstemmed 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title_short 11% Organic Photovoltaic Devices Based on PTB7‐Th: PC(71)BM Photoactive Layers and Irradiation‐Assisted ZnO Electron Transport Layers
title_sort 11% organic photovoltaic devices based on ptb7‐th: pc(71)bm photoactive layers and irradiation‐assisted zno electron transport layers
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6051392/
https://www.ncbi.nlm.nih.gov/pubmed/30027029
http://dx.doi.org/10.1002/advs.201700858
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